Semiconducting polymer

ABSTRACT

A semiconducting polymer formed from an insulator polymer and an ionic liquid is disclosed. In at least one embodiment, the semiconducting polymer may be formed from a homogenous blend of two or more insulator polymers and two or more ionic liquids. The homogenous mixture of non-conducting polymers and ionic liquid may be formed as a film of semiconducting polymer with a controllable thickness. The semiconducting polymer may be used in a multitude of different applications, including, but not limited to, storage devices.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. patent application Ser. No.13/399,460, filed Feb. 17, 2012, which claims the benefit of U.S.Provisional Patent Application No. 61/444,704, filed Feb. 19, 2011, theentireties of which is incorporated herein.

FIELD OF THE INVENTION

This invention is directed generally to conducting organic materials,and more particularly to semiconducting organic materials.

BACKGROUND

Semiconductors have long been formed from silicon. Silicon basedsemiconductors are limited by complex manufacturing processes needed tocreate the semiconductors, lack of flexibility and high cost. Thus, aneed exists for an improved semiconductor.

SUMMARY OF THE INVENTION

A semiconducting material formed from one or more insulator polymers andone or more ionic liquids is disclosed. The semiconducting material maybe synthesized by doping one or more of the insulator polymers with oneor more ionic liquids. The semiconducting material may be used in anumber of different applications, including, but not limited to, sensorsand storage devices.

The semiconducting material may be formed from one or more insulatorpolymers and one or more ionic liquids. The ionic liquid may include oneor more cationic and one or more anionic portions. The ionic liquid maybe, but is not limited to, one or more of 1,3-DialkylimidazoliumTetrafluoroborates, 1,3-Dialkylimidazolium Bromides,1,3-Diakylimidazolium Bistrifluoromethanesulfonimide,1-Alkyl-3-Aralkyl-Imidazolium and those ionic liquids derived fromnatural and renewable sources such as, but not limited to, glycerol,xylitol, sorbitol and choline chloride. The insulator polymer may be,but is not limited to, one or more of polyvinyl alcohol, poly acrylicacid, poly ethylene glycol, ethyl cellulose, polyolefins, polyesters,nonpeptide polyamines, polyamides, polycarbonates, polyalkenes,polyvinyl ethers, polyglycolides, cellulose ethers, polyvinyl halides,polyhydroxyalkanoates, polyanhydrides, polystyrenes, polyacrylates,polymethacrylates, polyurethanes, ethylcelluloses, polystyrenes,poly(ε-caprolactone), poly(d,l-lactic acid) and poly(d,l-lacticacid-co-glycolic acid) and copolymers and blends thereof. Thesemiconducting material may be a homogenous blend of the insulatorpolymer and the ionic liquid. In at least one embodiment, the insulatorpolymer may be formed from two or more insulator polymers. Similarly,the ionic liquid may be formed from two or more ionic liquids. Inanother embodiment, the insulator polymer and ionic liquid may form afilm. The film may have a predetermined thickness. The semiconductormaterial may be formed from the insulator polymer and the ionic liquidextruded under controlled temperature with a controllable thickness. Inanother embodiment, the semiconductor material formed from the insulatorpolymer and the ionic liquid may be formed into one or more fibers. Thesemiconducting material may be formed from up to 10 percent ionic liquidby weight with the remainder polymer and, more particularly, may bebetween zero percent and five percent ionic liquid by weight with theremainder polymer.

The semiconducting material may be used, in one example, to form one ormore storage devices. The storage devices may be configured to storedata and may be formed from one or more conductive layers positionedbetween a first insulator layer on a first side and a second insulatorlayer on a second side that is on a generally opposite side from thefirst side and a semiconducting film layer coupled to an outer surfaceof the first insulator. The conductive layer may be, but is not limitedto being, a carbon nanotube (CNT), zinc oxide, or gold. Thesemiconducting film layer may at least partially formed from a polyvinylacetate. The first insulator layer may be formed from an organicmaterial. In particular, the first insulator layer may be formed from anorganic poly-methyl-methacrylate material. The second insulator layermay be formed from an organic material. In particular, the secondinsulator layer may be formed from an organic poly-methyl-methacrylatematerial. A first electrode may be coupled to an outer surface of thesemiconducting film layer and a second electrode may be coupled to anouter surface of the second insulator layer. The first and secondelectrodes may be formed from any conducting material such as, but notlimited to, aluminum.

An advantage of this invention is that use of the semiconductingmaterial eliminates the need for using the restrictive siliconsemiconductor to more of an organic semiconductor that enables thecreation of affordable, flexible and expandable organic devices.

These and other embodiments are described in more detail below.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated in and form a part ofthe specification, illustrate embodiments of the presently disclosedinvention and, together with the description, disclose the principles ofthe invention.

FIG. 1 is a graph of examples of two different insulator polymers ofthis invention that are doped with two ionic liquids, glycerol andsorbitol and that display regulated levels of resistivity based on themixing between the insulators and the ionic liquid.

FIG. 2 is a perspective view of a schematic diagram of a storage deviceformed from the semiconducting material.

FIG. 3 is a hysteresis curve from the storage device.

DETAILED DESCRIPTION OF THE INVENTION

As shown in FIGS. 1-3, a semiconducting material 10 formed from one ormore insulator polymers and one or more ionic liquids is disclosed. Thesemiconducting material 10 may be synthesized by doping one or more ofthe insulator polymers with one or more ionic liquids. Thesemiconducting material 10 may be used in a number of differentapplications, including, but not limited to, sensors and storagedevices.

In at least one embodiment, the ionic liquid may be, but is not limitedto, one or more The ionic liquid may include one or more cationic andone or more anionic portions. The ionic liquid may be, but is notlimited to being, one or more of ionic marteials with a core structureof

and 1,3-Dialkylimidazolium Tetrafluoroborates, 1,3-DialkylimidazoliumBromides, 1,3-Diakylimidazolium Bistrifluoromethanesulfonimide,1-Alkyl-3-Aralkyl-Imidazolium, those ionic liquids derived from naturaland renewable sources such as ,but not limited to, glycerol, xylitol,sorbitol, choline chloride and materials having core structures of

In another embodiment, the ionic liquid may be glycerol formed duringthe transesterification of algae oil. The insulator polymer may be, butis not limited to, one or more of polyvinyl alcohol, poly acrylic acid,poly ethylene glycol, ethyl cellulose, polyolefins, polyesters,nonpeptide polyamines, polyamides, polycarbonates, polyalkenes,polyvinyl ethers, polyglycolides, cellulose ethers, polyvinyl halides,polyhydroxyalkanoates, polyanhydrides, polystyrenes, polyacrylates,polymethacrylates, polyurethanes, ethylcelluloses, polystyrenes,poly(ε-caprolactone), poly(d,l-lactic acid) and poly(d,l-lacticacid-co-glycolic acid) and copolymers and blends thereof. In oneembodiment, the semiconducting material may be a homogenous blend of theinsulator polymer and the ionic liquid. In one embodiment, the insulatorpolymer may be formed from two or more insulator polymers. Similarly,the ionic liquid may be formed from two or more ionic liquids.

The combined insulator polymer and the ionic liquid may form a film 12.The film 12 may have a predetermined thickness. The semiconductormaterial 10 may be formed from one or more insulator polymers and one ormore ionic liquids extruded under controlled temperature with acontrollable thickness. The semiconductor material 10 may form one ormore fibers from one or more insulator polymers and one or ionic liquidforms. The semiconductor material 10 may be synthesized by doping one ormore of the insulator polymers with one or more ionic liquids, thefunction of which is displayed in FIGS. 1 and 3.

The semiconducting material 10 may be formed from up to 10 percent ionicliquid by weight with the remainder polymer and, more particularly, maybe between zero percent and five percent ionic liquid by weight with theremainder polymer. The ionic liquid is added to the insulator polymer bydissolving the insulator polymer in water or an organic solvent andadding one or more ionic liquids to the mixture. The mixture may bestirred for between 1-30 minutes. In another embodiment, one or moreionic liquids may be mixed with one or more melted insulator polymers.The ionic liquid may be added to the polymer melt and then may be castthe melt to films. The percentage of added ionic liquid to insulatordepends on the level of conductivity needs to be acquired in thesemiconductor. For example, a mixture of PVA/PAA and 0.1 glycerolprovides a high conductivity.

The semiconducting material 10 may be used, in at least one example, asshown in FIG. 2, to form a storage device 14 capable of storing data.The storage device 14 may be formed from a conductive layer 16positioned between a first insulator layer 18 on a first side 20 and asecond insulator layer 22 on a second side 24 that is on a generallyopposite side from the first side 20. The conductive layer 16 may be,but is not limited to being, a carbon nanotube (CNT), zinc oxide, orgold. The storage device 14 may also include a semiconducting film layer28 coupled to an outer surface 30 of the first insulator 18. Thesemiconducting film layer 28 may be flexible and may be at leastpartially formed from a polyvinyl acetate (PVA). The semiconducting filmlayer 28 may be deposited on the device to serve as the semiconductinglayer. The first insulator layer 18 may be formed from an organicmaterial. In at least one embodiment, the first insulator layer 18 maybe formed from an organic poly-methyl-methacrylate material. The secondinsulator layer 22 may be formed from an organic material. In at leastone embodiment, the second insulator layer 22 may be formed from anorganic poly-methyl-methacrylate material.

The storage device 14 may include a first electrode 32 coupled to anouter surface 34 of the semiconducting film layer 28 and a secondelectrode 36 coupled to an outer surface 38 of the second insulatorlayer 22. The first and second electrodes 32, 36 are formed from anyconductive material, such as, but not limited to, aluminum. As such, thestorage device 14 may be formed from a first electrode 32, a firstinsulator layer 18, a conductive layer 16, a second insulator layer 22,a semiconducting film layer 28, and a second electrode 36.

The storage device 14 formed from the semiconducting material 10 mayoperate to read or write data, or both, with less than 2 volts, therebyenabling the devices 14 to be fully compatible with logic operationvoltages. The storage device 14 may also be

The foregoing is provided for purposes of illustrating, explaining, anddescribing embodiments of this invention. Modifications and adaptationsto these embodiments will be apparent to those skilled in the art andmay be made without departing from the scope or spirit of thisinvention.

I claim:
 1. A semiconducting material, comprising: at least oneinsulator polymer; and at least one ionic liquid.
 2. The semiconductormaterial of claim 1, wherein the at least one ionic liquid is selectedfrom the group consisting of 1,3-Dialkylimidazolium Tetrafluoroborates,1,3-Dialkylimidazolium Bromides, 1,3-DiakylimidazoliumBistrifluoromethanesulfonimide, 1-Alkyl-3-Aralkyl-Imidazolium, glycerol,xylitol, sorbitol, choline chloride and glycerol formed during thetransesterification of algae oil.
 3. The semiconductor material of claim1, wherein the at least one insulator polymer is selected from the groupconsisting of polyvinyl alcohol, poly acrylic acid, poly ethyleneglycol, ethyl cellulose, polyolefins, polyesters, nonpeptide polyamines,polyamides, polycarbonates, polyalkenes, polyvinyl ethers,polyglycolides, cellulose ethers, polyvinyl halides,polyhydroxyalkanoates, polyanhydrides, polystyrenes, polyacrylates,polymethacrylates, polyurethanes, ethylcelluloses, polystyrenes,poly(ε-caprolactone), poly(d,l-lactic acid) and poly(d,l-lacticacid-co-glycolic acid) and copolymers.
 4. The semiconductor material ofclaim 1, wherein the semiconducting material is a homogenous blend ofthe at least one insulator polymer and the at least one ionic liquid. 5.The semiconductor material of claim 1, wherein at least one insulatorpolymer comprises at least two insulator polymers.
 6. The semiconductormaterial of claim 1, wherein at least one ionic liquid comprises atleast two ionic liquids.
 7. The semiconductor material of claim 1,wherein the at least one insulator polymer and at least one ionic liquidform a film.
 8. The semiconductor material of claim 7, wherein the filmhas a predetermined thickness.
 9. The semiconductor material of claim 1,wherein the semiconductor material formed of the at least one insulatorpolymer and the at least one ionic liquid is extruded under controlledtemperature with a controllable thickness.
 10. The semiconductormaterial of claim 1, wherein the semiconductor material formed of the atleast one insulator polymer and the at least one ionic liquid forms atleast one fiber.
 11. The semiconducting material of claim 1, wherein theat least one ionic liquid comprises up to 10 percent ionic liquid byweight.
 12. The semiconducting material of claim 1, wherein the at leastone ionic liquid comprises up to five percent ionic liquid by weight.13. A storage device, comprising: at least one device formed from aconductive layer positioned between a first insulator layer on a firstside and a second insulator layer on a second side that is on agenerally opposite side from the first side; and a semiconducting filmlayer coupled to an outer surface of the first insulator.
 14. Thestorage device of claim 13, wherein the semiconducting film layer is atleast partially formed from a polyvinyl acetate.
 15. The storage deviceof claim 13, wherein the first insulator layer is formed from an organicmaterial.
 16. The storage device of claim 15, wherein the firstinsulator layer is formed from an organic poly-methyl-methacrylatematerial.
 17. The storage device of claim 13, wherein the secondinsulator layer is formed from an organic material.
 18. The storagedevice of claim 17, wherein the second insulator layer is formed from anorganic poly-methyl-methacrylate material.
 19. The storage device ofclaim 13, further comprising a first electrode coupled to an outersurface of the semiconducting film layer and a second electrode coupledto an outer surface of the second insulator layer.
 20. The storagedevice of claim 19, wherein the first and second electrodes are formedfrom aluminum.